Hawaii Community College
Hazardous Material and Hazardous Waste
Hawaii Community College
Hazardous Material and Hazardous Waste
Management Program
September 2000
Revised December 2002
Dear Colleagues
The Hawaii Community College has a fundamental obligation to safeguard the
health, safety, and welfare of our students, personnel, and the visiting public
whenever they participate in an official College activity. It is the policy of
the College to provide for and maintain, through implementation of
environmental, health and safety programs, conditions and practices that provide
safe and healthful campus environment. In keeping with this commitment, the
Hazardous Material and Hazardous Waste Management Program was developed.
The revised Hazardous Material and Hazardous Waste Management Program (HMMP) is
designed to ensure the protection of College personnel and the environment from
potential hazards associated with hazardous materials and hazardous waste. It
will also assist the college in achieving compliance with applicable federal,
state and county regulations. The HMMP is for your reference in managing
hazardous materials and hazardous waste at Hawaii Community College.
It is our responsibility as members of the University of Hawaii community to be
committed to ensure the environmental, health and safety of our campus. We are
committed to follow and comply with the Hazardous Material and Hazardous Waste
Management Program. This HMMP will be effective immediately.
____________________________
Sandra Sakaguchi
Provost
Hawaii Community College
December 2002
Purpose
This program outlines requirements for the management of hazardous materials and
the disposal of hazardous waste at Hawaii Community College (Hawaii CC) and West
Hawaii Community College (West Hawaii CC). These requirements are based on
federal, state and county regulations. Adherence to this program will ensure the
proper management of hazardous materials and hazardous wastes, reduce overall
costs (by reducing disposal cost and minimizing the use of hazardous materials),
and avoid potential civil and/or criminal liabilities. This plan is applicable
to both Hawaii CC and West Hawaii CC. Failure to comply with these requirements
may subject Hawaii CC, West Hawaii CC and/or individuals to fines and civil or
criminal prosecution. Additionally, proper management of hazardous materials
reduces disposal costs.
Applicability
This program applies to all personnel that purchase, store, transport, manage,
use, and dispose of hazardous materials and/or hazardous wastes.
Responsibilities
All applicable personnel must become familiar with the hazardous materials in
their area and with the Hawaii CC Hazardous Materials and Hazardous Waste
Management Program. They will contact the UHCC Environmental Safety Specialist,
Ph: 808-956-9464 or University of Hawaii Environmental Health and Safety Office
(EHSO); Ph: 808- 956-8660 if in doubt about the requirements of this program or
about how to properly dispose of waste.
I. RESPONSIBLE PERSONNEL
A. All personnel must
Become familiar with the hazardous materials in their area and with this
HAWAII CC hazardous material and hazardous waste management program.
Use authorization to purchase form (Attachment 1) to obtain approval for the
purchase of hazardous material.
Submit an authorization to use hazardous material form (Attachment 2) for
grant approval
Provide a semi-annual inventory of hazardous materials (Attachment 3) and a
annual inventory of hazardous wastes (Attachment 4).
Store and label waste properly.
Properly make a waste determination according to federal and state
regulations.
B. Designated program coordinators
The Directors of Administrative Services (DOAS) is responsible for overall
coordination of the Hazardous Material and Hazardous Waste Management Program.
The DOAS shall ensure that the Program Coordinators listed below have current
training.
The following personnel are designated as responsible for the implementation of
this program in their respected areas of responsibility:
Agriculture Agriculture Instructor(s)
Apprenticeship Apprenticeship Coordinator
Art Art Instructor
Automotive Automotive Instructor(s)
Auto Body Auto Body Instructor(s)
Biological Sciences Biology Instructor (s)
Carpentry Carpentry Instructor(s)
Ceramics Ceramic Instructor
Diesel Mechanics Diesel Instructor(s)
Drafting Drafting Instructor(s)
Electricity Electrical Instructor(s)
Electronics Electronic Instructor(s)
Food Service Food Service Instructor(s)
Nursing Nursing Instructor(s)
Welding Welding Instructor(s)
All above personnel are required to attend the initial Hazardous Waste Generator
training and the annual refresher Hazardous Waste Generator training. EHSO will
provide the training and upon satisfactory completion of the training will issue
training certificates.
This Hazardous Material Management Program is subject for review annually to
maintain current practices, methods, and regulatory requirements. Revisions to
this program require EHSO approval.
II. HAZARDOUS MATERIAL MANAGEMENT
A. Training certificates. HAWAII CC program coordinators must submit copies of
their training certificates to the DOAS prior to purchasing or disposing of
hazardous chemicals.
B. Authorization to purchase hazardous materials. The DOAS approval is required
for the purchase or requisition of all hazardous materials. The Authorization to
Purchase Hazardous Materials Form (Attachment 1), must be complete and submitted
to DOAS at the time any purchase order for hazardous materials is initiated. If
approved, a copy of the form will be provided to you for attachment to your
purchase order or requisition. The purpose of the DOAS approval is to ensuring
the safe storage, handling and eventual disposal of the material while
minimizing the cost to HAWAII CC. All request should be submitted for approval
for purchase two weeks prior to purchasing chemicals.
C. Approval to use hazardous materials. As part of the grant approval process
(ORS Form 5, item 4 under PI certification) a specific form for the use of
certain hazardous materials has been developed (Attachment 2). This form is
similar to those already in place for the use of radioactive and biohazard
materials.
D. Inventory Control Procedures
1. Semi-Annual Inventory of Hazardous Materials. HAWAII CC programs that store
hazardous materials are required to submit semi-annual inventories to the DOAS.
The semi-annual inventory form, Attachment 3, will help HAWAII CC manage
existing hazardous materials, monitor on-going usage, and prevent unnecessary
accumulation. Inventories are due October 1 and May 1 or each year. As part of
the inventory procedure, HAWAII CC programs are required to inspect the
condition of all hazardous material containers to ensure that hazardous
materials are stored in containers which are in good condition and which are
properly labeled.
2. Annual Inventory of Hazardous Wastes. HAWAII CC programs that generate
hazardous wastes are required to submit annual waste inventories to the DOAS.
Waste inventory forms (Attachment 4) shall be submitted to the DOAS on May 1.
The DOAS will submit a copy of the inventory form to the UHCC Environmental
Safety Specialist so that the DOT hazard classes and EPA waste codes can be
added. As part of the inventory procedure, HAWAII CC programs are required to
inspect the condition of all hazardous material containers to ensure that
hazardous materials are stored in containers which are in good condition and
which are properly labeled.
3. Inventory of Special Wastes. While certain wastes are not hazardous, they
also cannot be disposed of in a sanitary landfill or down the drain, and may
necessitate special disposal procedures. These non-hazardous wastes should be
included in Waste Inventory Form for proper disposal.
E. Audit Program. The audit program will assist in maintaining a safe working
and academic environment. DOAS and/or the Environmental Health and Safety Office
will conduct periodic audits of the campus to review the current operations with
respect to all applicable safety, health and environmental policies and
regulations. The following issues will be reviewed: hazardous material storage,
hazardous and acutely hazardous waste accumulation, Material Safety Data Sheet
availability, hazardous waste accumulation areas, and emergency plans. A report
indicating any corrective actions that are necessary and suggesting any
improvements will be provided by the DOAS.
F. Storage of Material Safety Data Sheets (MSDS). All chemical manufacturers and
suppliers of hazardous chemicals must furnish an MSDS with each initial shipment
and furnish new MSDS information upon request. MSDSs generally contain
information such as the following:
Chemical composition
Physical characteristics and chemical properties
Fire, explosion and reactivity hazards
Health hazard information and symptoms of overexposure
Protective equipment recommendations
Handling and storage precautions
Cleanup and disposal procedures
Emergency first aid procedures
Federal and state law requires that written MSDSs must be kept in proximity to
the area where products are stored and must be readily available to all
employees at any time. MSDSs must also be available for emergency personnel or
any state or federal agency that requests them. It is the responsibility of the
supervisor in each area to ensure that all MSDSs are kept in an accessible
storage area and are updated. If an MSDS is missing or incomplete, it is likely
that you can obtain a copy from the Internet or from the manufacturer. Requests
for missing MSDSs should be made in writing and sent by fax, and a copy of the
request should be kept in your file.
III. HAZARDOUS WASTE MANAGEMENT
A. Waste Determination. It is the responsibility of the generators to make the
waste determination for their waste. The responsibility is to determine whether
the waste is a hazardous waste (RCRA hazard waste or non-RCRA hazardous waste)
or a non-hazardous waste. All waste determinations must be made according to the
specific federal and state definitions summarized in Attachment 5. The UHCC
Environmental Safety Specialist (808-956-9464) can and will assist you in making
a waste determination. A waste determination must be done as soon as waste is
collected into a waste container. The waste determination will be documented on
the Chemical Waste Tag. Most facilities produce wastes consistent in character.
Therefore what is often the most confusing aspect of the regulations –
characterization and classification – becomes a periodic verification function.
1. What is a waste? A waste is:
A useless by-product of an operation
A material which is to be disposed
Any material which can no longer be used
A manufacturing or process by-product
2. How do I determine if a waste is hazardous?
a. Contact the Environmental Health and Safety Office. The UH EHSO Office
(808-956-8660) or the Environmental Safety Specialist for the Community Colleges
(808-956-9464) will assist you in making a determination of whether a waste is
hazardous.
b. Review the Material Safety Data Sheets. MSDSs may provide information that
will assist you and the EHSO office in making a proper hazardous waste
determination.
B. Accumulation of Wastes.
1. Limits on Waste Generation. To maintain the status of conditionally exempt
small quantity generator, HAWAII CC may not generate more than 100 kilograms
(approximately one half of a 55-gallon drum, 27 gallons, or 220 pounds) of
hazardous waste. HAWAII CC also may not generate more than 1 kilogram (2.2
pounds) of acute hazardous waste in one month.
2. Limits on Waste Accumulation. To maintain the status of conditionally exempt
small quantity generator, HAWAII CC may not have more than 1000 kilograms
(approximately five 55-gallon drums, or 275 gallons, or 2200 pounds) of total
accumulated hazardous waste and no more than 1 kilogram (2.2 pounds) of
accumulated acute hazardous waste at any time.
3. Designation of Waste Management Area. HAWAII CC programs generating hazardous
waste should establish a safe area near the point of generation for the
temporary storage of that waste before disposal by a licensed contractor. The
area should be neat and orderly, containers should not be stacked upon one
another or containers of liquid should not be stored on their side. The DOAS
will hire a licensed hazardous waste contractor to transport the waste to an EPA
permitted hazardous waste treatment, storage and disposal facility.
C. Storage of Hazardous Waste
1. Waste Containers
a. Labeling. All hazardous waste containers must be labeled with the Chemical
Waste Tags (Attachment 6). The Chemical Waste Tag must be filled out as soon as
waste is collected into a waste container.
Please fill out tags completely. All information requested on the tag is
necessary to assist in the proper labeling of the waste container. Any
incomplete tags are just as dangerous as no tags at all.
Chemical constituents are required with the estimated.
Please provide pH for all liquids.
Hazardous waste determination. Please check the appropriate items on the tag
to accurately describe the waste characteristic.
b. Closed Containers. All hazardous waste containers must remain closed except
when waste is being added to them.
c. Containers in Good Condition. Containers used for wastes must be in good
condition (i.e. no rusting, cracks or structural defects). If a container is
broken or begins to leak, the material must be transferred to a container in
good condition. The material composition must be compatible with the material to
be stored and incompatible materials must not be stored in proximity to one
another. Package materials in sturdy cardboard boxes or plastic waste
containers. Cushion the material in the containers to prevent breakage. If
cardboard boxes are used which originally held other chemicals, the name of the
chemical must be covered over or defaced. Failure to do so constitutes improper
marking as to contents and is an EPA and OSHA regulation violation.
Secondary Containment. Secondary containment are required for containers of
liquid waste under the following circumstances:
1. When waste is stored in 55-gallon drums
2. When the waste is stored on the floor.
3. When the waste is stored in a fume hoods that have a drain.
4. When the waste is stored within four (4) feet of sink
5. When necessary to separate incompatibles or high hazard wastes.
Plastic tubs can be used as secondary containments. Consult with the UHCC
Environmental Safety Specialist (808-956-9464) regarding appropriate containment
when a 55-gallon drum is used to collect waste.
d. Separate Incompatible Materials/Waste. Incompatible materials shall be
segregated by HAZARD CLASS, i.e. Toxic-Reactive-Ignitable-Corrosive-Oxidizers.
Examples of incompatible materials are: acids/bases, organics/oxidizers, and
flammable liquids/oxidizers. Unknowns and high hazard materials such as
cyanides, organic peroxides, pyrophorics, water reactives and explosives shall
be packaged separately regardless of quantity. Training will be provided to
assist in segregation of incompatible materials. If there are any questions,
please call the UHCC Environmental Safety Specialist (808-956-9464) for
assistance.
D. Hazardous Waste Disposal. The disposal of hazardous waste requires that a
licensed hazardous waste contractor be hired to dispose of the waste. Please
submit the Annual Hazardous Waste Inventory form to the DOAS. All waste that you
wish to have disposed must be listed on the form.
1. Drain disposal prohibited. No hazardous materials/waste may be disposed of
down the drain. All liquid prior to drain disposal (except known clean water)
shall be reviewed prior to any drain disposal. In addition, Hawai’i County
Ordinances prohibit disposal of the following additional items down the drain:
Fats and greases, if their concentration and physical dispersion results in
separation and adherence to sewer structures.
Storm water, surface water, groundwater, roof runoff, subsurface drainage,
cooling water, swimming pool water or other unpolluted drainage.
Liquid or vapor having a temperature of >150 degrees Fahrenheit.
Any water or waste containing >100 ppm, by weight, of fat, oil or grease.
Gasoline, benzene, naphtha, fuel oil, or other flammable or explosive liquid,
solid or gas.
Garbage that has not been properly shredded. Garbage from commercial food
establishments is prohibited.
Ashes, cinders, sand, mud, straw, shavings, metal, glass, rags, feathers, tar,
plastics, wood, paunch manure or any other solid or viscous substance capable of
causing obstruction to the flower in sewers.
Water or wastes having a pH lower than 5.5 or higher than 9.5 having any other
corrosive property capable of causing damage to the sewage works or its
personnel.
Water or wastes containing a toxic or poisonous substance of sufficient
quantity to injure or interfere with any sewage treatment process or cause a
hazard to humans or animals.
Noxious or malodorous gas or explosive liquids or substance capable of
endangering public property and safety, or creating a public nuisance.
IV. EMERGENCY SPILL PROCEDURES
You must have a specific spill emergency plan and provide information and
training to individuals working in your area regarding the plan. It is a good
idea to post the emergency procedures and emergency phone numbers in the work
area. Personnel working with hazardous chemicals should be able to answer the
question: "What would I do if this material spilled?"
Spill kits with instructions, absorbents, reactants, and protective equipment
should be available to clean up minor spills. A minor spill is one that does not
spread rapidly, does not endanger people or property except by direct contact,
does not endanger the environment, and the workers in the area are capable of
handling safely without the assistance of safety and emergency personnel. All
other chemical spills are considered major.
The following are general procedures for the handling of spills.
1. In the event of a spill, attend to anyone who may have been contaminated or
hurt, if it can be done without endangering yourself.
2. Turn on the fume hood(s) and open windows where this can be done without
endangering yourself.
3. If flammable materials are spilled, de-energize electrical devices if it can
be done without endangering yourself.
A. Minor Spills
If you have any questions regarding spill clean up requirements, please
contact the Director of Administrative Service (974-7614), Community College
Environmental Safety Specialist (808-956-9464), Environmental Health and Safety
Office at the UH Manoa campus (808-956-8660).
Ensure protective apparel is resistant to the spilled material. Neutralize
acids and bases, if possible using neutralizing agents such as sodium carbonate
or sodium bisulfate.
Control the spread of liquids by containing the spill. Absorb liquids by
adding appropriate absorbent materials, such as vermiculite or sand, from the
spill's outer edges toward the center. Paper towels and sponges may also be used
as absorbent material, but this should be done cautiously considering the
character of the spilled material.
Collect and contain the cleanup residue and any materials used to clean up the
spill by scooping them into a plastic bucket or other appropriate container and
properly disposing of the waste as hazardous waste.
Decontaminate the area and affected equipment. Ventilating the spill area may
be necessary.
Document what happened, why, what was done, and what was learned. Such
documentation can be used to avoid similar instances in the future. Major
incidents are almost always preceded by numerous near misses.
B. Major Spills
If the spill is major, evacuate and secure the area from all personnel.
If flammable liquid is spill, secure all ignition sources.
If the spill is major contact the Fire Department (911), Director of
Administrative Service (974-7614), UHCC Environmental Safety Specialist
(808-956-9464) Environmental Health and Safety Office at the UH Manoa Campus
(808-956-8660).
C. Reporting Requirements
After the initial spill response, contact the Director of Administrative
Service (974-7614), UHCC Environmental Safety Specialist (808-956-9464),
Environmental Health and Safety Office at the UH Manoa campus (808-956-8660) to
determine whether there are any federal or state reporting requirements. Some
reporting obligations are immediate, and must be made within 24 hours.
V. SPECIFIC INFORMATION ON THE DISPOSAL OF VARIOUS MATERIALS/WASTE
The individual possessing or generating the material/waste retains the primary
responsibility for the material/waste. The Director of Administrative Service
(974-7614), UHCC Environmental Safety Specialist at (808-956-6494) and the
Environmental Health and Safety Office at the UH Manoa campus (808-956-8660)
provides information on requirements and assistance in handling the materials.
Specific information on various types of materials is given below.
BATTERIES: Lithium, nickel/cadmium or mercury batteries shall be stored at the
hazardous waste accumulation site for contract disposal. Vehicle batteries are
recyclable and arrangements with local vendors can be made. Operations and
Maintenance handle disposal of batteries from State vehicles.
BIOLOGICAL MATERIALS: For biohazardous wastes, refer to the published University
biohazardous waste disposal guidelines or contact the EHSO Biological Safety
Officer (808-956-3197) for information concerning the handling and disposal of
biological materials. Remains from dissections shall be properly disposed of.
COMPRESSED GASES: Compressed gas cylinders should be returned to the vendor. A
return agreement with the vendor should be included in the contract. Without
such an agreement the return or disposal of the cylinders is difficult and very
costly, contact the UHCC Environmental Safety Specialist (808-956-9464) for
assistance.
CONTROLLED SUBSTANCES: The handling and disposal of controlled substances (i.e.
drugs and other substances listed in 21 CFR 1308) are the responsibility of the
permit holder.
FLUORESCENT LIGHT BALLASTS: The HAWAII CC Auxiliary Services Department
(974-7369) removes non-leaking ballast. Ballast which may contains PCBs, contact
the UHCC Environmental Safety Specialist (808-956-9464), Environmental Health
and Safety Office at the UH Manoa campus (808-956-8660) for assistance
concerning leaking ballast or any ballast known to contain PCBs.
FLUORESCENT LIGHT TUBES: The HAWAII CC Auxiliary Services Department (974-7369)
removes and disposes of fluorescent light tubes.
HAZARDOUS CHEMICALS AND HAZARDOUS WASTE: The “College” will hire a contractor to
dispose of hazardous wastes. Efforts should be made to determine if others could
use excess hazardous chemicals in the department or facility prior to submitting
for contract disposal. Chemicals considered non-hazardous waste (see
"Non-hazardous Waste" below) could be disposed of in the municipal sanitary
landfill or sanitary sewer.
MERCURY: Items containing functional mercury (e.g. light switches, barometers
and thermometers) shall be stored at a hazardous waste accumulation site for
contract disposal.
MIXED WASTE: Mixed waste is defined as materials that possess a radioactive or
biological hazard as well as an unrelated chemical hazard (e.g. potassium
dichromate solution contaminated with Carbon-14). Contact the Environmental
Health and Safety Office at the UH Manoa campus Radiation Safety (808-956-6475)
as applicable for assistance in the proper disposal of these materials.
NON-HAZARDOUS WASTE: Listed below in Table 1 are typical laboratory chemicals
that are not considered hazardous wastes by the U.S. Environmental Protection
Agency. If the facility refuse contract permits the disposal of the solid
chemicals in Table 1, then they can be disposed of as ordinary trash. The
containers should be labeled and marked “non-hazardous” to mitigate any concern
by the refuse collectors. Alternatively, the materials can be collected for
disposal as non-hazardous waste in the periodic waste disposal shipments. Liquid
chemicals or chemical solutions can be disposed of to the sanitary sever, if the
requirements of the applicable county ordinances or the facility industrial
waste water discharge permit are met. Alternatively, the materials can be
collected for disposal as non-hazardous waste in the periodic waste disposal
shipments.
TABLE 1: NON-HAZARDOUS WASTE
Sugars
(e.g., sucrose, glucose, mannose)
Silica Gel
Starch
Alumina (aluminum oxide)
Naturally occurring Amino Acids
Calcium Fluoride
Citric Acid and its Sodium, Potassium, Magnesium, Calcium and Ammonium Salts.
Lactic Acid and its Sodium, Potassium, Magnesium, Calcium and Ammonium, Salts
Sodium, Potassium, Calcium, Strontium, and Ammonium Sulfates
Sodium, Potassium, Calcium, Magnesium, Strontium and Ammonium Phosphates
Sodium, Potassium, Magnesium and Ammonium Chlorides
Sodium, Potassium, Magnesium, and Calcium Borates
Silicon Dioxide
Sodium, Potassium, Ammonium Acetates
Boron, Magnesium, Copper Oxides
Sodium, Potassium, Magnesium, Calcium, and Ammonium Carbonates
OILS AND TRANSFORMER FLUID: The DOAS will assist with disposal of used pump oil.
Used motor oil is recyclable through local vendors. Operations and Maintenance
handle used motor oil from University vehicles.
Transformer fluid will be handled on a case-by-case basis, contact the
Environmental Health and Safety Office at the UH Manoa campus (808-956-8660) for
assistance. The following requirements apply to used oil:
Used oil may only be stored in containers that are in good condition and not
leaking.
Containers, aboveground storage tanks, and fill pipes must be labeled or
marked clearly with the words “Used Oil.”
Upon detection of a release of used oil, a generator must stop the release,
contain the used oil, clean up and manage properly the used oil and other
materials, and if necessary, repair or replace any leaking used oil storage
containers. If a release of used oil occurs, contact the Director of
Administrative Services (974-7614), Environmental Safety Specialist
(808-956-9464), Environmental Health and Safety Office at the UH Manoa campus
(808-956-8660) for information regarding cleanup, and special regulatory
reporting requirements which may apply.
PAINT WASTE (Auto body): Excess paint or waste paint containing cadmium,
chromium, lead or mercury will not be recycled but will be disposed of as
hazardous waste. Other paint waste generated by the Auto body Program will be
stored in a marked container labeled, “Paint Waste for Recycling”. On a regular
basis, the paint waste will be processed through the paint solvent recycler.
After recycling, the remaining sludge will be checked for ignitibility. If the
sludge is ignitable, it will be disposed of as hazardous waste. If it is not
ignitable, it will be disposed in the municipal sanitary landfill. Thinner
solvent extract can be used as product.
PHOTOGRAPHIC CHEMICALS: Photographic fixer will must be stored in capped
container and labeled, “Fixer for Recycling”. Photographic fixer solution may
contain silver salts after use. Silver is an EPA toxic characteristic waste and
must be recycled or disposed of as a hazardous waste. If your facility has a
silver recovery unit, it should be used to process the used fixer in accordance
with the manufacturing instructions. This would include ensuring that the
effluent from the unit meets the requirements for safe drain disposal and that
the unit filter, when full, is sent for recycling. If your facility does not
have a silver recovery unit, there are contractors who will furnish one for a
fee or for the value of the silver recovered. Alternatively, the used fixer
solution can be handled and disposed of as a hazardous waste.
RADIOACTIVE MATERIALS: Refer to the University Radiation Safety Manual or
contact the UH Manoa campus (808-956-8660) for information concerning the proper
handling and disposal of radioactive material.
SHARPS AND GLASSWARE: Glassware not contaminated with radiological, biological
or hazardous chemical material shall be placed in a puncture resistant container
labeled "glass" or "broken glass". It will be picked up by the Auxiliary
Services staff and disposed of. Refer to the published University biohazardous
waste disposal guidelines or contact the Environmental Safety Specialist
(808-956-9464) for information on the handling and disposal of sharps or
glassware contaminated with biological or infectious material. Refer to the
University Radiation Safety Manual or contact the Environmental Health and
Safety Office at the UH Manoa campus (808-956-8660) for information on the
proper handling and disposal of sharps or glassware contaminated with
radioactive material. Glassware or sharps contaminated with hazardous chemicals
should be rinsed to decontaminate them and then disposed of as non-contaminated
glassware or sharps (i.e. placed in a sharps container). Broken glassware
contaminated with hazardous chemicals should be placed in a puncture resistant
container (e.g. bottle, plastic container or can over-pack), labeled with the
name of the chemical and disposed of as hazardous chemical waste.
VI. HAZARDOUS WASTE MINIMIZATION
A. Buying Chemicals in Smaller Amounts.
The "large economy size" may cost less to buy, but disposal costs, in most
cases, are several times the initial cost of the material. Many of the bottles
of excess or waste chemicals sent for disposal are full or 3/4 full. Everyone
needs to try to accurately estimate the amount of a chemical they expect to use.
B. Recycling and Redistribution
Efforts should be made to find someone in the laboratory or department who can
use the hazardous material before it is submitted to the DOAS as waste for
contract disposal.
C. Use of Less Hazardous or Non-hazardous Materials
The following provides some examples of the use of less hazardous or
non-hazardous materials; everyone is encouraged to think of some others that may
be applicable to their research or instructional materials.
Cleaning Solutions: Chromerge, chromic acid and dichromate cleaning solutions
are not desirable from a waste disposal prospective, as they cannot be made
non-hazardous and are expensive to dispose of. There are many non-toxic
biodegradable cleaning solutions that can be used instead of chromic acid. For
extremely dirty glassware a product called Nochromix, which uses sulfuric acid
and an organic oxidizer in place of chromium can be used. While this requires
neutralization of the acid for ordinary disposal, it is far less costly to
dispose of than chromium solutions. A number of alternative cleaning solutions
are listed below. These are all available from Fisher Scientific, who has the
University contract for laboratory supplies. NoChromix, Alconox, Liquinox liquid
detergent, Citranox, Fisherbrand sparkleen, and FL-70 Concentrate.
Drying Agents: The safest common drying agents are calcium chloride, silica gel,
molecular sieves and calcium sulfate (Drierite). These are recommended because
of their low toxicity and stability. Drying agents that pose varying degrees of
hazard and disposal problems include:
Phosphorus pentoxide which generates highly corrosive phosphoric acid and heat
on contact with water. This material also has to be disposed of as a hazardous.
Magnesium perchlorate (Dehydrite) which is a strong oxidizer and may cause fires
or explosions on contact with organic materials. This material has to be
disposed of as a hazardous waste.
Thermometers: Mercury thermometers should be replaced with non-mercury
thermometers whenever possible. Broken mercury thermometers create spills that
are a potential health hazard, time consuming to clean up, and are one of the
most expensive hazardous wastes to dispose of. Non-mercury thermometers with
equivalent accuracy are available for temperature ranges of –20 to 250 degrees
Centigrade. Check your laboratory supply catalog for more information. If
mercury containing equipment is used, then a mercury spill kit and personnel
knowledgeable in its use is required in the laboratory or facility.
HAWAII COMMUNITY COLLEGE - UNIVERSITY OF HAWAI’I
PROCUREMENT AUTHORIZATION FOR HAZARDOUS MATERIALS
An approved (signed) copy of this form must accompany any request, purchase
order or requisition for the procurement of all hazardous materials.
NAME: _________________________________________
(Instructor/Program Coordinator)
DEPARTMENT: __________________________ PHONE NO., EXT.: ___________
LOCATION: __________________________ PURCHASE ORDER NO.: ___________
Chemical Name Solid/Liquid/Gas Amount
(gallon, lbs) Usage Plan
Estimated Usage Period
Instructor/Program Coordinator__________________________ DATE: __________
(Signature)
Dean/Director___________________________________________ DATE:____________
(Signature
PLEASE SEND THE COMPLETED FORM TO: Director of Administrative Services (DOAS).
FOR DOAS USE ONLY
DOAS APPROVAL: ___________________________________ DATE: ________________
APPROVAL NO.: _____________________________________
ATTACHMENT 1
UNIVERSITY OF HAWAI’I AT MANOA
ENVIRONMENTAL HEALTH & SAFETY OFFICE
HAZARDOUS MATERIAL MANAGEMENT PROGRAM
APPROVAL FOR THE USE OF HAZARDOUS MATERIAL
For Research Grants
1. Principal
Investigator:________________________________________________________
2. Project
Title:________________________________________________________________
3. If your project will involve any of the types of hazardous materials listed
below, please provide a list of the chemical name(s) and approximate amounts of
the materials to be used, information on how the material will be used and
stored, also information on any special safety measures that will be taken. The
information is needed to ensure the materials are stored, used and disposed of
in accordance with the applicable Federal and State regulations.
a) Explosive materials (e.g., ammonium perchlorate, picric acid or picrates,
azides, acetylides or fulminates of heavy metals, aromatic di or tri nitro
compounds such as dinitrophenol or trinitrotoluene, nitroglycerine, RDX and
tetrazene).
b) Water reactive chemicals (e.g., alkali metals such as sodium, potassium or
lithium; metal hydrides such as lithium aluminum hydride, sodium borohydride or
lithium hydride; calcium carbide, ethyldichlorosilane and phosphides).
c) Flammable or poison gases (e.g. methane, ethylene, chlorine, phosgene and
hydrogen sulfide).
d) Organic peroxides (e.g., methyl ethyl ketone peroxide or peracetic acid).
e) Highly toxic materials (e.g., cyanides, osmium tetroxide, phosphorus,
strychnine, pentaborane, or any material with a LD50 [oral rat] of 50mg/kg or
less).
f) Flammable liquids (i.e., materials with a flash point of 140 degrees
Fahrenheit or less) in quantities of 60 gallons or more at any one time.
ATTACHMENT 2
4. If your project will involve the use of controlled substances (i.e.,
materials listed in 21 CFR 1308 by the U.S. Drug Enforcement Agency such as
cocaine, chloral hydrate, morphine, and sodium barbital), provide the number of
the required Federal or State permit for possession and use of these materials.
5. I agree to: (1) comply with the University of Hawaii at Manoa Hazardous
Material Management Program (HMMP) requirements and any additional requirements
provided by the Environmental Health and Safety Office that are necessary to
ensure compliance with Federal and State regulations, (2) inform the
Environmental Health and Safety Office if there are any amendments to the
project which affect the types of hazardous material listed above, and (3)
transfer or properly dispose of all my hazardous material as specified in the
HMMP prior to leaving the University or transferring to a different laboratory.
I believe the above information is accurate and complete.
--------------------------------------------------------
---------------------------------
PRINCIPAL INVESTIGATOR DATE
--------------------------------------------------------
-----------------------------------
DEAN/DIRECTOR DATE
PLEASE SEND THE COMPLETED FORM TO: HSO 2040 East-West Road Attention: Hazardous
Material Management Officer. The Hazardous Material Management Officer may be
contacted at 956-3198 or Fax 956-3205, if you have questions.
6. The use of the hazardous materials listed above is approved subject to the
special requirements listed below.
--------------------------------------------------------------
-----------------------------------
HAZARDOUS MATERIAL MANAGEMENT OFFICER DATE
SPECIAL REQUIREMENTS:
College_________________ UNIVERSITY OF HAWAI’I
Community College
HAZARDOUS CHEMICAL INVENTORY FORM (SEMI - ANNUAL)
This form assists University of Hawaii with proper management of our hazardous
material and hazardous waste and to ensure that materials are safely stored and
handled. You should provide a complete inventory of all stored hazardous
materials. If additional space is needed, you may use an attached sheet using
the same format. If at a later date you obtain materials not previously listed,
please submit an amended form.
I. PRODUCT NAME II. CHEMICAL NAME Primary
Hazard
Warning Physical State (solid, liquid or solution) Container Size Amount
(gal, lb)s Qty
INSTRUCTOR/PROGRAM COORDINATOR:
___________________________________ PHONE NO.:_________________ LOCATION:
_________________________
(Printed Name)
___________________________________ Date: __________________________________
(Signature)
PLEASE SEND THE COMPLETED FORM TO: Director of Administrative Services. The DOAS
may be contacted if you have any questions.
ATTACHMENT 3
SAMPLE
College_______________ UNIVERSITY OF HAWAI’I
Community College
HAZARDOUS CHEMICAL INVENTORY FORM (SEMI - ANNUAL)
This form assists University of Hawaii with proper management of our hazardous
material and hazardous waste and to ensure that materials are safely stored and
handled. You should provide a complete inventory of all stored hazardous
materials. If additional space is needed, you may use an attached sheet using
the same format. If at a later date you obtain materials not previously listed,
please submit an amended form.
III. PRODUCT NAME IV. CHEMICAL NAME Primary
Hazard
Warning Physical State (solid, liquid or solution) Container Size Amount
(gal, lb)s Qty
Acetic Acid, Glacial Flammable Liquid 1 gal 1 gal 5
Enamel Paint Naphtha ether, mineral spirit Flammable Liquid 1 gal 1 gal 10
Carter’s Rubber Cement Naphtha, Hexane, Propyl alcohol Flammable Liquid 4 oz 4
oz 48
INSTRUCTOR/PROGRAM COORDINATOR:
________Dr. George Bush_____________ PHONE NO.:______x7777______ LOCATION:
___Science Bldg, Rm 205_____
(Printed Name)
___________________________________ Date: __________________________________
(Signature)
PLEASE SEND THE COMPLETED FORM TO: Director of Administrative Services. The DOAS
may be contacted if you have any questions.
ATTACHMENT 3
College_______________ UNIVERSITY OF HAWAI’I
Community College
HAZARDOUS WASTE INVENTORY FORM (ANNUAL)
This form assists Hawaii Community College with proper management of our
hazardous waste. If you have any hazardous or non-hazardous waste being stored
for disposal, please provide the information requested. If additional space is
needed, you may use an attached sheet using the same format. If at a later date
you generate wastes not previously listed, please submit an amended form. EHSO
will complete columns 8 and 9, DOT Class and EPA Waste Code.
Chemical Name/Product
(Chemical constituents) Physical State (solid, liquid or solution) Amount
(gal, lbs) Container Size Container Type Hazard Category pH) DOT Class (EHSO
only) EPA Waste Code (EHSO only)
INSTUCTOR/PROGRAM COORDINATOR:
___________________________________ PHONE NO.: _________________ LOCATION:
_______________________
(Printed Name)
___________________________________ Date: __________________________________
(Signature)
PLEASE SEND THE COMPLETED FORM TO: Director of Administrative Services. The DOAS
may be contacted if you have any questions.
ATTACHMENT 4
SAMPLE
College________________ UNIVERSITY OF HAWAI’I
Community College
HAZARDOUS WASTE INVENTORY FORM (ANNUAL)
This form assists Hawaii Community College with proper management of our
hazardous waste. If you have any hazardous or non-hazardous waste being stored
for disposal, please provide the information requested. If additional space is
needed, you may use an attached sheet using the same format. If at a later date
you generate wastes not previously listed, please submit an amended form. EHSO
will complete columns 8 and 9, DOT Class and EPA Waste Code.
Chemical Name/Product
(Chemical constituents) Physical State (solid, liquid or solution) Amount
(gal, lbs) Container Size Container Type Hazard Category pH) DOT Class (EHSO
only) EPA Waste Code (EHSO only)
Solvent waste—Acetone 5%, methanol 20%, mineral spirits50%, water 20% Liquid 55
gal 55 gal Drum metal flam N/A
Spray paint—mineral spirit Liquid under pressure 8 oz 16 oz Metal Flam N/A
Acid solution—hydrochloric acid 45%,, sulfuric acid Liquid 4 liter 4 liter Glass
corr 1
INSTRUCTOR/PROGRAM COORDINATOR:
________Dr. George Bush___________ PHONE NO.: ____x7555_______ LOCATION:
___Science bldg rm 205___
(Printed Name)
___________________________________ Date: __________________________________
(Signature)
PLEASE SEND THE COMPLETED FORM TO: Director of Administrative Services. The DOAS
may be contacted if you have any questions.
ATTACHMENT 4
Procedure for Making
Hazardous Waste Determinations
All wastes must be screened to determine whether they are hazardous. A hazardous
waste is one which because of its quantity, concentration, or physical,
chemical, or infectious characteristics may cause, or significantly contribute
to an increase in mortality or an increase in serious irreversible, or
incapacitating reversible, illness; or pose a substantial present or potential
hazard to human health or the environment when improperly treated, stored,
transported, or disposed of, or otherwise managed. The EPA has determined that
the following meet the definition of a hazardous waste:
a) A waste which is listed as hazardous in the regulations (40 CFR 261);*
b) A mixture that includes a listed hazardous waste; or
c) A waste which exhibits any of the four following characteristics;
ignitability, corrosivity, reactivity, or toxicity.
*Note: The complete text of the hazardous waste regulations is available online
at www.epa.gov/epahome/cfr40.htm.
The following procedures must be used to determine if a waste is hazardous. If
it is, the procedures will identify the appropriate EPA hazardous waste number
for each waste, which will in turn determine disposal requirements:
(i.) Determine the proper name of the waste and its specific source.
(ii.) Check the EPA’s hazardous waste lists in the following order:
(a.) “U” list of toxic wastes (40 CFR 261.33f).
(b.) “P” List of acutely hazardous waste (40 CFR 261.33e). See Attachment 6.
(c.) “K” List of hazardous wastes from specific sources (40 CFR 261.32).
(d.) “F” List (40 CFR 261.31) for a non-specific source of waste.
(iii.) If the waste is not one the “U” List, the “P” List, the “K” List or the
“F” List, you must determine whether the waste exhibits any of following four
characteristics:
ATTACHMENT 5
(a.) Ignitability. A waste that exhibits the characteristic of ignitability has
the EPA hazardous waste number of D001. See 40 CFR §261.20.
(b.) Corrosivity. A waste that exhibits the characteristic of corrosivity has
the EPA hazardous waste number of D002. See 40 CFR §261.22.
(c.) Reactivity. A waste that exhibits the characteristic of reactivity has the
EPA hazardous waste number of D003. See 40 CFR §261.23.
(d.) Toxicity. A waste that exhibits the characteristic of reactivity will have
and the EPA hazardous waste number of D004 through D043. See 40 CFR §261.24.
LIST OF ACUTELY HAZARDOUS WASTE (P-CODED WASTE)
The following materials are hazardous wastes if and when they are intended to be
discarded (40 CFR 261.33):
1. Any commercial chemical products, or manufacturing chemical intermediate
having the generic name listed below.
2. Any specification commercial chemical or product or chemical intermediate
having the generic name listed below.
3. Any residue remaining in a container that is not empty. P-coded containers
must have their contents removed and be triple rinsed with an appropriate
solvent before they are legally empty and no longer regulated.
4. Any residue resulting from the clean-up of a spill of a P-coded waste.
5. The phrase “commercial chemical product or manufacturing chemical
intermediate having a generic name listed below” refers to a chemical substances
which is manufactured or formulated for commercial or manufacturing use which
consists of the commercially pure grade of the chemical, any technical grades of
the chemical that are produced or marketed, and all formulations in which the
chemical is the sole active ingredient.
Hazardous Waste No. Chemical Abstracts No. Chemical Name
P023 107-20-0 Acetaldehyde, chloro-
P002 591-08-2 Acetamide, N-(aminothioxomethyl)-
P057 640-19-7 Acetamide, 2-fluoro-
P058 62-74-8 Acetic acid, fluoro-, sodium salt
P002 591-08-2 1-Acetyl-2-thiourea
P003 107-02-8 Acrolein
P070 116-06-3 Aldicarb
P203 1646-88-4 Aldicarb sulfone
P004 309-00-2 Aldrin
P005 107-18-6 Allyl alcohol
P006 20859-73-8 Aluminum phosphide
P007 2763-96-4 5-(Aminomethyl)-3-isoxazolol
P008 504-24-5 4-Aminopyridine
P009 131-74-8 Ammonium Picrate
P119 7803-55-6 Ammonium Vanadate
P099 506-61-6 Argintate (1-), bis(cyano-C-), potassium
P010 7778-39-4 Arsenic acid (H3AsO4)
P012 1327-53-3 Arsenic oxide (As2O3)
P011 1303-28-2 Arsenic oxide (As2O5)
P011 1303-28-2 Arsenic pentoxide
P012 1327-53-3 Arsenic trioxide
P038 692-42-2 Arsine, diethyl-
P036 696-28-8 Arsenous dichloride, phenyl-
P054 151-56-4 Aziridine
P067 75-55-8 Aziridine, 2-methyl-
P013 542-62-1 Barium cyanide
P024 106-47-8 Benzenamine, 4-chloro-
P077 100-01-6 Benzenamine, 4-nitro
P028 100-44-7 Benzene (chloromethyl)-
P042 51-43-4 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-
P046 122-09-8 Benzeneethanamine, alpha,alpha-dimethyl-
P014 108-98-5 Benzenethiol
P127 1563-66-2 7-Benzofuranol, 2,3-dihydro-2-2-dimethyl-, methylcarbamate
P188 57-64-7 Benzoic acid, 2-hydroxy,compd, with
(3aS-cis)-1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethylpyrrolo [2,3-b]indol-5-yl
methylcarbamate ester (1:1)
P001 81-81-2 2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenylbutyl)-, & salts,
when present at concentrations greater than 0.3%.
P028 100-44-7 Benzyl chloride
P015 7740-47-7 Beryllium powder
P017 598-31-2 Bromoacetone
P018 357-57-3 Brucine
P045 39196-18-4 2-Butanone, 3,3-dimethyl-1-(methylthio)-, o-[methylamino,
carbonyl] oxime
P021 592-01-8 Calcium cyanide
P189 55285-14-8 Carbamic acid, [(dibutylamino)-thio]methyl-,2,3-dihydro-2,2-dimethyl-7-benzofuranyl
ester
P191 644-64-4 Carbamic acid, dimethyl-,
1-[(diemthylamino)carbonyl]-5-methyl-1H-pyrazol-3-yl ester
P192 119-38-0 Carbamic acid, dimethyl-,
3-methyl-1-(1-methylethyl)-1H-pyrazol-5-yl ester
P190 1129-41-5 Carbamic acid, methyl-, 3-methylphenyl ester
P127 1563-66-2 Carbofuran
P022 75-15-0 Carbon disulfide
P095 75-44-5 Carbonic dichloride
P189 55285-14-8 Carbosulfan
P023 107-20-0 Chloroacetaldehyde
P024 106-47-8 p-Chloroaniline
P026 5344-82-1 1-(o-Chlorophenyl) thiourea
P027 542-76-7 3-Chloropropionitrile
P029 544-92-3 Copper cyanide (202CuCN)
P202 64-00-6 m-Cumenyl methylcarbamate
P030 ------------ Cyanides (soluble cyanide salts) not otherwise specified
P031 460-19-5 Cyanogen
P033 506-77-4 Cyanogen chloride (CNCl)
P034 131-89-5 2-Cyclohexyl-4,6-dinitrophenol
P016 542-88-1 Dichloromethyl ether
P036 696-28-6 Dichlorophenylarsine
P037 60-57-1 Dieldrin
P038 692-42-2 Diethylarsine
P041 311-45-5 Diethyl-p-nitrophenyl phosphate
P040 297-97-2 O,O-Diethyl O-pyrazinyl phosphorothioate
P043 55-91-4 Diisopropylfluorophosphate (DFP)
P004 309-00-2 1,4,5,8-Dimethanonaphthalene,
1,2,3,4,10,10-hexa-chloro-1,4,4a,5,8,8a,-hexahydro-(1alpha,4alpha,4abeta,5alpha,8alpha,8abeta)-
P060 465-73-6 1,4,5,8-Dimethanonaphthalene,
1,2,3,4,10,10-hexa-chloro-1,4,4a,5,8,8a-hexahydro-,
(1alpha,4alpha,4abeta,5beta,8beta,8abeta)-
P037 60-57-1 2,7:3,6-Dimethanonaphth[2,3-b]
oxirene,3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-(1aalpha,2beta,2aalpha,3beta,6beta,6aalpha,
7beta,7aalpha)-
P051 72-20-8 2,7:3,6-Dimethanonaphth[2,3,-b]
oxirene,3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-,(1aalpha,2beta,2abeta,3alpha,6alpha,6abeta,7beta,7aalpha)-,
& metabolites
P044 60-51-5 Dimethoate
P046 122-09-8 alpha,alpha-Dimethylphenethylamine
P191 644-64-4 Dimetilan
P047 534-52-1 4,6,Dinitro-o-cresol, & salts
P048 51-28-5 2,4,-Dinitrophenol
P020 88-85-7 Dinoseb
P085 152-16-9 Diphosphoramide, octamethyl-
P111 107-49-3 Diphosphoric acid, tetraethyl ester
P039 298-0404 Disulfoton
P049 541-53-7 Dithiobiuret
P185 26419-73-8 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-,O-[(methylamino)-carbonyl]
oxime
P050 115-29-7 Endosulfan
P088 145-73-3 Endothall
P051 72-20-8 Endrin, & metabolites
P042 51-43-4 Epinephrine
P031 460-19-5 Ethanedinitrile
P194 23135-22-0 Ethanimidothioc acid, 2-(dimethylamino)-N-{[(methylamino)
carbonyl] oxy}-2-oxo-, methyl ester
P066 16752-77-5 Ethanimidothioic acid, N-{[(methylamino) carbonyl]oxy}-, methyl
ester
P101 107-12-0 Ethyl cyanide
P054 151-56-4 Ethyleneimine
P097 52-85-7 Famphur
P056 7782-41-4 Fluorine
P057 640-19-7 Fluoroacetamide
P058 62-74-8 Fluoroacetic acid, sodium salt
P198 23422-53-9 Formetanate hydrochloride
P197 17702-57-7 Formparanate
P065 628-86-4 Fulminic acid, mercuric salt
P059 76-44-8 Heptachlor
P062 757-58-4 Hexaethyl tetraphosphate
P116 79-19-6 Hydrazinecarbothioamide
P068 60-34-4 Hydrazine, methyl-
P063 74-90-8 Hydrocyanic acid
P063 74-90-8 Hydrogen cyanide
P096 7803-51-2 Hydrogen phosphide
P060 465-73-6 Isodrin
P192 119-38-0 Isolan
P202 64-00-6 3-Isopropylphenyl N-methylcarbamate
P007 2763-96-4 3(2H)-Isoxazolone, 5-(aminomethyl)-
P196 15339-36-3 Manganese, bis(dimethylcarbamodithioato-S,S’)-
P196 15339-36-3 Manganese dimethyldithiocarbamate
P092 62-38-4 Mercury, (acetato-O)phenyl-
P065 628-86-4 Mercury fulminate
P082 62-75-9 Methanamine, N-methyl-N-nitroso-
P064 624-83-9 Methane, isocyanato-
P016 542-88-1 Methane, oxybis(chloro-
P112 509-14-8 Methane, tetranitro-
P118 75-70-7 Methanethiol, trichloro-
P198 23422-53-9 Methanimidamide, N,N-diemthyl-N’-{3-[[(methylamino)-carbonyl]oxy]-phenyl}-,
monohydrochloride
P197 17702-57-7 Methanimidamide, N,N-dimethyl-N’-{2-methyl-4-[[(methylamino)
carbonyl]oxy]phenyl}-
P050 115-29-7 6,9,-Methano-2,4,3-benzodioxathiepin,
6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide
P059 76-44-8 4,7,-Methano-1H-indene,
1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro-
P199 2032-65-7 Methiocarb
P066 16752-77-5 Methomyl
P068 60-34-4 Methyl hydrazine
P064 624-83-9 Methyl isocyanate
P069 75-86-5 2-Methyllactonitrile
P071 298-00-0 Methyl parathion
P190 1129-41-5 Metolcarb
P128 315-08-4 Mexacarbate
P072 86-88-4 alpha-Naphthylthiourea
P073 13463-39-3 Nickel carbonyl (NiCO)
P074 557-19-7 Nickel cyanide (NiCN)
P075 54-11-5 Nicotine & salts
P076 10102-43-9 Nitric oxide
P077 100-01-6 p-Nitroaniline
P078 10102-44-0 Nitrogen dioxide
P076 10102-43-9 Nitrogen oxide (NO)
P078 10102-44-0 Nitrogen oxide (NO2)
P081 55-63-0 Nitroglycerine
P082 62-75-9 N-Nitrosodimethylamine
P084 4549-40-0 N-Nitrosomethylvinylamine
P085 152-16-9 Octamethylpyrophosphoramide
P087 20816-12-0 Osmium Tetroxide (OsO4)
P088 145-73-3 7-Oxabicyclo(2.2.1)heptane-2,3-dicarboxylic acid
P194 23135-22-0 Oxamyl
P089 56-38-2 Parathion
P034 131-89-5 Phenol, 2-cyclohexyl-4,6-dinitro-
P048 51-28-5 Phenol, 2,4-dinitro
P047 534-52-1 Phenol, 2-methyl-4,6-dinitro- & salts
P020 88-85-7 Phenol, 2-(1-methylpropyl)-4,6-dinitro-
P009 131-74-8 Phenol, 2,4,6-trinitro-, ammonium salt
P128 315-18-4 Phenol, 4-(dimethylamino)-3,5-dimethyl-, methylcarbamate (ester)
P199 2032-65-7 Phenol, (3,5-dimethyl-4-(methylthio)-, methylcarbamate
P202 64-00-6 Phenol, 3-(1-methylethyl)-, methylcarbamate
P201 2631-37-0 Phenol, 3-methyl-5-(1-methylethyl)-, methylcarbamate
P092 62-38-4 Phenylmercury acetate
P093 103-85-5 Phenylthiourea
P094 298-02-2 Phorate
P095 75-44-5 Phosgene
P096 7803-51-2 Phosphine
P041 311-45-5 Phosphoric acid, diethyl 4-nitrophenyl ester
P039 298-04-4 Phosphorodithioic acid, O,O-diethyl S-[2-(ethylthio)ethyl] ester
P094 298-02-2 Phosphorodithioic acid, O,O-diethyl S-[(ethylthio)methyl] ester
P044 60-51-5 Phosphorodithioic acid, O,O-dimethyl S-[2-(methylamino)-2-oxoethyl]
ester
P043 55-91-4 Phosphorofluoridic acid, bis(1-methylethyl) ester
P089 56-38-2 Phosphorothioic acid, O,O-diethyl O-(4-nitrophenyl) ester
P040 297-97-2 Phosphorothioic acid, O,O-diethyl O-pyrazinyl ester
P097 52-85-7 Phosphorothioic acid, O-{4-[(dimethylamino)sulfonyl] phenyl}
O,O-dimethyl ester
P071 298-00-0 Phosphorothioic acid, O,O-dimethyl O-(4-nitrophenyl) ester
P204 57-47-6 Physostigmine
P188 57-64-7 Physostigmine salicylate
P110 78-00-2 Plumbane, tetraethyl-
P098 151-50-8 Potassium cyanide (KCN)
P099 506-61-6 Potassium silver cyanide
P201 2631-37-0 Promecarb
P070 116-06-3 Propanal, 2-methyl-2-(methylthio)-, O-[(methylamino)carbonyl]
oxime
P203 1646-88-4 Propanal, 2-methyl-2-(methyl-sulfonyl)-, O-[(methylamino)
carbonyl] oxime
P101 107-12-0 Propanenitrile
P027 542-76-7 Propanenitrile, 3-chloro-
P069 75-86-5 Propanenitrile, 2-hydroxy-2-methyl-
P081 55-63-0 1,2,3,-Propanetriol, trinitrate
P017 598-31-2 2-Propanone, 1-bromo-
P102 107-19-7 Propargyl alcohol
P003 107-02-8 2-Propenal
P005 107-18-6 2-Propen-1-ol
P067 75-55-8 1,2-Propylenimine
P102 107-19-7 2-Propyn-1-ol
P008 504-24-5 4-Pyridinamine
P075 54-11-5 Pyridine, 3-(1-methyl-2-pyrrolidinyl)-, (S)-, & salts
P204 57-47-6 Pyrrolo[2,3-b]indol-5-ol,
1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethyl-, methylcarbamate (ester, (3aS-cis)-
P114 12039-52-0 Selenious acid, dithallium (thallous) salt
P103 630-10-4 Selenourea
P104 506-64-9 Silver cyanide (AgCN)
P105 26628-22-8 Sodium azide
P106 143-33-9 Sodium cyanide (NaCN)
P108 57-24-9 Strychnidin-10-one, & salts
P018 357-57-3 Strychnidin-10-one, 2,3-dimethoxy-
P108 57-24-5 Strychnine & salts
P115 7446-18-6 Sulfuric acid, dithallium (thallous) salt
P109 3689-24-5 Tetraethyldithiopyrophosphate
P110 78-00-2 Tetraethyl lead
P111 107-49-3 Tetraethyl pyrophosphate
P112 509-14-8 Tetranitromethane
P062 757-58-4 Tetraphosphoric acid, hexaethyl ester
P113 1314-32-5 Thallic oxide
P113 1314-32-5 Thallium oxide (Tl2O3)
P114 12039-52-0 Thallium (I) selenite (thallous selenite)
P115 7446-18-6 Thallium (I) sulfate (thallous sulfate)
P109 3689-24-5 Thiodiphosphoric acid, tetraethyl ester
P045 39196-18-4 Thiofanox
P049 541-53-7 Thioimidodicarbonic diamide (H2NCS)2NH
P014 108-98-5 Thiophenol
P116 79-19-6 Thiosemicarbazide
P026 5344-82-1 Thiourea, (2-chlorophenyl)-
P072 86-88-4 Thiourea, 1-naphthalenyl-
P093 103-85-5 Thiourea, phenyl-
P185 26419-73-8 Tirpate
P123 8001-35-2 Toxaphene
P118 75-70-7 Trichloromethanethiol
P119 7803-55-6 Vanadic acid, ammonium salt
P120 1314-62-1 Vanadium Oxide (V2O5) vanadium pentoxide
P084 4549-40-0 Vinylamine, N-methyl-N-nitroso-
P001 81-81-2 Warfarin, & salts, when present at concentrations greater than 0.3%
P205 137-30-4 Zinc, bis(dimethylcarbamodithioato-S,S’)-,
P121 557-21-1 Zinc cyanide [ Zn (CN)2]
P122 1314-84-7 Zinc phosphide (Zn3P2) when in concentrations greater than 10%
P205 137-30-4 Ziram